The dication [(eta(6)-C6Me6)Ru(eta(6)-C20H10 10)](2+) in propylene carbonate solution exhibits a sequence of reduction processes that is either metal-centered [Ru(II)/Ru(l)/Ru(O)] or ligand-centered. The marginally stable Ru(I) monocation [(eta(6)-C6Me6)Ru (=eta(6)-C20H10,o)](+) has been characterized by EPR spectroscopy. The electrochemistry Of C20H10 and EPR features of its stable monoanion [C20H10](-) have also been revisited.
Angelici, R.J., Zhu, B., Fedi, S., Laschi, F., Zanello, P. (2007). Electrochemical and EPR studies of the corannulene ruthenium(II) sandwich complex [(η6-C6Me6)Ru(η6-C20H10)](SbF6)2. INORGANIC CHEMISTRY, 46(25), 10901-10906 [10.1021/ic7015512].
Electrochemical and EPR studies of the corannulene ruthenium(II) sandwich complex [(η6-C6Me6)Ru(η6-C20H10)](SbF6)2
Fedi, Serena;Laschi, Franco;Zanello, Piero
2007-01-01
Abstract
The dication [(eta(6)-C6Me6)Ru(eta(6)-C20H10 10)](2+) in propylene carbonate solution exhibits a sequence of reduction processes that is either metal-centered [Ru(II)/Ru(l)/Ru(O)] or ligand-centered. The marginally stable Ru(I) monocation [(eta(6)-C6Me6)Ru (=eta(6)-C20H10,o)](+) has been characterized by EPR spectroscopy. The electrochemistry Of C20H10 and EPR features of its stable monoanion [C20H10](-) have also been revisited.
| File | Dimensione | Formato | |
|---|---|---|---|
|
07-3.pdf
non disponibili
Tipologia:
Post-print
Licenza:
NON PUBBLICO - Accesso privato/ristretto
Dimensione
91.39 kB
Formato
Adobe PDF
|
91.39 kB | Adobe PDF | Visualizza/Apri Richiedi una copia |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
https://hdl.handle.net/11365/7002
Attenzione
Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo