The analysis of the EXAFS spectrum of nickel substituted Cu,Zn superoxide dismutase excludes tetrahedral coordination for the nickel ion. The results are better in agreement with a five-coordinated stereochemistry which is probably obtained through a bidentate coordination of Asp 81. Our findings are in complete agreement with the spectral data reported in the literature.
Mangani, S., Orioli, P.L., Carloni, P. (1994). Exafs Investigation On Nickel Substituted Cu,zn Bovine Superoxide-dismutase. INORGANICA CHIMICA ACTA, 216(1-2), 121-124 [10.1016/0020-1693(93)03704-E].
Exafs Investigation On Nickel Substituted Cu,zn Bovine Superoxide-dismutase
Mangani, Stefano;
1994-01-01
Abstract
The analysis of the EXAFS spectrum of nickel substituted Cu,Zn superoxide dismutase excludes tetrahedral coordination for the nickel ion. The results are better in agreement with a five-coordinated stereochemistry which is probably obtained through a bidentate coordination of Asp 81. Our findings are in complete agreement with the spectral data reported in the literature.
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https://hdl.handle.net/11365/34426
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