The 5H,11H-pyrrolo [2, 1-c][1,4] benzothiazepine ring system has been prepared by two synthetic pathways, involving the intramolecular nucleophilic displacement on 1-(2-fluorobenzyl)-2-mercaptomethylpyrrole or the Pummerer rearrangement of 1-(2-ethoxycarbonylmethylsulfinyl-benzyl)pyrrole followed by in situ cyclization, respectively. © 1990.
Garofalo, A., Nacci, V., Corelli, F., Campiani, G. (1990). Polycondensed heterocycles. V. Synthesis of 5H,11H-Pyrrolo[2,1-c][1,4]benzothiazepine. HETEROCYCLES, 31(7), 1291-1300 [10.3987/com-90-5391].
Polycondensed heterocycles. V. Synthesis of 5H,11H-Pyrrolo[2,1-c][1,4]benzothiazepine
Nacci, Vito;Corelli, Federico;Campiani, Giuseppe
1990-01-01
Abstract
The 5H,11H-pyrrolo [2, 1-c][1,4] benzothiazepine ring system has been prepared by two synthetic pathways, involving the intramolecular nucleophilic displacement on 1-(2-fluorobenzyl)-2-mercaptomethylpyrrole or the Pummerer rearrangement of 1-(2-ethoxycarbonylmethylsulfinyl-benzyl)pyrrole followed by in situ cyclization, respectively. © 1990.File in questo prodotto:
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