The electrochemistry of [Cu(OEP)] and [Ni(OEP)] are compared with the mixed-valence π-cations [Cu (OEP){radical dot} / 2]2+ and [Ni (OEP){radical dot} / 2]2+. These electrochemical studies, carried out with cyclic voltammetry and hydrodynamic voltammetry, show that the mixed valence π-cations have distinct electrochemical properties, although the differences between the [M(OEP)]+/0 and [M (OEP){radical dot} / 2]2+ / 0 processes are subtle. © 2007 Elsevier B.V. All rights reserved.
Scheidt, W.R., Buentello, K.E., Ehlinger, N., Cinquantini, A., Fontani, M., Laschi, F. (2008). Mixed-valence porphyrin π-cation radical derivatives: Electrochemical investigations. INORGANICA CHIMICA ACTA, 361(6), 1722-1727 [10.1016/j.ica.2006.12.028].
Mixed-valence porphyrin π-cation radical derivatives: Electrochemical investigations
Laschi, Franco
2008-01-01
Abstract
The electrochemistry of [Cu(OEP)] and [Ni(OEP)] are compared with the mixed-valence π-cations [Cu (OEP){radical dot} / 2]2+ and [Ni (OEP){radical dot} / 2]2+. These electrochemical studies, carried out with cyclic voltammetry and hydrodynamic voltammetry, show that the mixed valence π-cations have distinct electrochemical properties, although the differences between the [M(OEP)]+/0 and [M (OEP){radical dot} / 2]2+ / 0 processes are subtle. © 2007 Elsevier B.V. All rights reserved.
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https://hdl.handle.net/11365/24107
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