Ternary five-vertex arachno-type cobalt-tin-chalcogene clusters are accessible by means of insertion of the chalcogen elements S and Se into the unbridged Co−Sn bond of the stannanediyl cobalt complexes [(η5-CpR)Co−Sn{CH(SiMe3)2}2] (1-3). They display a rich spectroelectrochemistry. CV and EPR measurements reveal that the relevant HOMO orbitals are strongly transition metal centered.
Schneider, J.J., Hagen, J., Spickermann, D., Blaser, D., Boese, R., Fabrizi De Biani, F., et al. (2000). Synthesis, structure, and spectroelectrochemical investigation of novel ternary Co/S(Se)/Sn clusters derived from binary cobalt stannanediyl complexes. CHEMISTRY-A EUROPEAN JOURNAL, 6(2), 237-246 [10.1002/(SICI)1521-3765(20000117)6:2<237::AID-CHEM237>3.0.CO;2-Q].
Synthesis, structure, and spectroelectrochemical investigation of novel ternary Co/S(Se)/Sn clusters derived from binary cobalt stannanediyl complexes
Fabrizi De Biani, Fabrizia;Laschi, Franco;Zanello, Piero
2000-01-01
Abstract
Ternary five-vertex arachno-type cobalt-tin-chalcogene clusters are accessible by means of insertion of the chalcogen elements S and Se into the unbridged Co−Sn bond of the stannanediyl cobalt complexes [(η5-CpR)Co−Sn{CH(SiMe3)2}2] (1-3). They display a rich spectroelectrochemistry. CV and EPR measurements reveal that the relevant HOMO orbitals are strongly transition metal centered.
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https://hdl.handle.net/11365/20026
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