Analyses at the Cu-K, Fe-K and Mn-K edge were performed to study the green, marbled (green and yellow), blue and blackish (deep greyish olive green) glass slabs decorating three sectilia panels from the archaeological site of Faragola. Results indicate that all slabs were made by mixing siliceous sand with natron, sometimes probably mixed with small percentages of plant ash. Cu2+ and Pb antimonates should be responsible for the opaque green colours. The dark green and yellow portions of the marbled slabs are respectively comparable to the slabs comprising only one of these colours. Cu2+ together with Ca antimonates probably produced light blue slabs, whereas cobalt was used to produce dark blue slabs. We consider it possible that the abundance ratio of Fe2+ /Fe3+ and the complex Fe3+ S2- would have an effect on the blackish slabs. The contribution of Mn cannot be ascertained even if it could have played a role in darkening glass colour. The comparison between the chemical composition of Faragola samples and several glass reference groups provided no conclusive evidence of provenance; whereas, the presence of a secondary local workshop can be hypothesized.

Gliozzo, E., SANTAGOSTINO BARBONE, A., D'Acapito, F., Turbanti, I., Turchiano, M., & Volpe, G. (2010). The sectilia panels of Faragola (Ascoli Satriano, southern Italy): a multi-analytical study of the green, marbled, blue and blackish glass slabs. ARCHAEOMETRY, 52(Part 3), 389-415 [10.1111/j.1475-4754.2009.00493.x].

The sectilia panels of Faragola (Ascoli Satriano, southern Italy): a multi-analytical study of the green, marbled, blue and blackish glass slabs

GLIOZZO, E.;SANTAGOSTINO BARBONE, A.;TURBANTI, I.;
2010

Abstract

Analyses at the Cu-K, Fe-K and Mn-K edge were performed to study the green, marbled (green and yellow), blue and blackish (deep greyish olive green) glass slabs decorating three sectilia panels from the archaeological site of Faragola. Results indicate that all slabs were made by mixing siliceous sand with natron, sometimes probably mixed with small percentages of plant ash. Cu2+ and Pb antimonates should be responsible for the opaque green colours. The dark green and yellow portions of the marbled slabs are respectively comparable to the slabs comprising only one of these colours. Cu2+ together with Ca antimonates probably produced light blue slabs, whereas cobalt was used to produce dark blue slabs. We consider it possible that the abundance ratio of Fe2+ /Fe3+ and the complex Fe3+ S2- would have an effect on the blackish slabs. The contribution of Mn cannot be ascertained even if it could have played a role in darkening glass colour. The comparison between the chemical composition of Faragola samples and several glass reference groups provided no conclusive evidence of provenance; whereas, the presence of a secondary local workshop can be hypothesized.
Gliozzo, E., SANTAGOSTINO BARBONE, A., D'Acapito, F., Turbanti, I., Turchiano, M., & Volpe, G. (2010). The sectilia panels of Faragola (Ascoli Satriano, southern Italy): a multi-analytical study of the green, marbled, blue and blackish glass slabs. ARCHAEOMETRY, 52(Part 3), 389-415 [10.1111/j.1475-4754.2009.00493.x].
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11365/17251
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