Synthesis, electrochemical studies, density functional analysis and X-ray structures of trans,cis,cis-[RuCl2(N-methylimidazole)2(SbPh3)2] and trans,cis,cis-[RuCl2(4-methyl pyrimidine)2(SbPh3)2]. The role of C-H…N and C-H...Cl interactions in pyrimidine pairings and in tuning the angular approach of imidazole residues to metals