The photoreactivity of the title compound has been examined in MeOH, PriOH, MeCN, and MeCN/as-dimethylhydrazine solutions. A ketenimine and a spiroazirine intermediate account for the final products as well as for the transients observed in the flash photolysis experiments. It is also found that acid catalysis plays an important role in the reaction of spiroazirine to oxazolopyridine. © 1990 American Chemical Society.
Donati, D., Ponticelli, F., Bicchi, P., Meucci, M. (1990). Flash Photolysis Study of 3-Methylisoxazolo[5,4-b]pyridine. THE JOURNAL OF PHYSICAL CHEMISTRY, 94(13), 5271-5274 [10.1021/j100376a020].
Flash Photolysis Study of 3-Methylisoxazolo[5,4-b]pyridine
Donati, Donato;Ponticelli, Fabio;Bicchi, Paola;Meucci, Mario
1990-01-01
Abstract
The photoreactivity of the title compound has been examined in MeOH, PriOH, MeCN, and MeCN/as-dimethylhydrazine solutions. A ketenimine and a spiroazirine intermediate account for the final products as well as for the transients observed in the flash photolysis experiments. It is also found that acid catalysis plays an important role in the reaction of spiroazirine to oxazolopyridine. © 1990 American Chemical Society.
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https://hdl.handle.net/11365/6829
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