Irradiation of tetrathienyltetrathiafulvalenes in an oxygen saturated solution gives tetrathienyl substituted 1,2,5,8-tetrathiecine-6,7-diones, via singlet oxygen generation followed by cycloaddition onto the TTF double bond and a final rearrangement process. The thermal and photochemical behaviour and reductive methylation of this new class of macro-heterocyclic system have also been investigated. © 2013 Elsevier Ltd. All rights reserved.
Charlton, A., Donati, D., Fusi, S., Murphy, P.J., Ponticelli, F. (2013). Self sensitized photooxidation of tetrathienyltetrathiafulvalenes: synthesis of thienyl substituted 1,2,5,8-tetrathiecine-6,7-dione, a new heterocyclic system. TETRAHEDRON LETTERS, 54(10), 1227-1229 [10.1016/j.tetlet.2012.12.080].
Self sensitized photooxidation of tetrathienyltetrathiafulvalenes: synthesis of thienyl substituted 1,2,5,8-tetrathiecine-6,7-dione, a new heterocyclic system
Donati D.;Fusi S.;Ponticelli F.
2013-01-01
Abstract
Irradiation of tetrathienyltetrathiafulvalenes in an oxygen saturated solution gives tetrathienyl substituted 1,2,5,8-tetrathiecine-6,7-diones, via singlet oxygen generation followed by cycloaddition onto the TTF double bond and a final rearrangement process. The thermal and photochemical behaviour and reductive methylation of this new class of macro-heterocyclic system have also been investigated. © 2013 Elsevier Ltd. All rights reserved.
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https://hdl.handle.net/11365/44447
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