An NMR method for determining carbon spin-lattice relaxation rates under three different proton perturbation conditions is proposed. Thymidine is investigated as a model system. Dynamical and structural information is obtained by comparison of the carbon-13 relaxation rates obtained under broad-band pulse and selected pulse conditions with standard spin-lattice relaxation rates. © 1987.
Rossi, C., Marchettini, N., Pogliani, L., Laschi, F., Niccolai, N. (1987). Structural and Dynamic Studies of the Relaxation Effects Induced By Proton Perturbation During C-13 Spin-lattice Relaxation Rate Measurements. CHEMICAL PHYSICS LETTERS, 136(6), 506-509 [10.1016/0009-2614(87)80507-9].
Structural and Dynamic Studies of the Relaxation Effects Induced By Proton Perturbation During C-13 Spin-lattice Relaxation Rate Measurements
Rossi, C.;Marchettini, N.;Laschi, F.;Niccolai, N.
1987-01-01
Abstract
An NMR method for determining carbon spin-lattice relaxation rates under three different proton perturbation conditions is proposed. Thymidine is investigated as a model system. Dynamical and structural information is obtained by comparison of the carbon-13 relaxation rates obtained under broad-band pulse and selected pulse conditions with standard spin-lattice relaxation rates. © 1987.
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https://hdl.handle.net/11365/33639
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