Solid state and solution EPR and electrochemical studies have been carried out on a series of complexes of copper(II) with differently substituted Phenanthrolines and cinnamate ligands. Spectra were recorded on binary complexes with cinnamate ligand and on a series of ternary complexes with the same anion and 1,10-Phenanthroline, 2,9-dimethyl-1,10-o-Phenanthroline or 4,7-dimethyl-1,10-o-Phenanthroline additional ligands, respectively. The electrochemistry of the same copper complexes was studied in N,N-dimethylformamide solvent. The results of both EPR and electrochemical experimetns can be correlated with electronic and steric effects attributable to the methyl substituents on the Phenanthroline ligand

ZORODDU M., A., PILO M., I., Seeber, R., Pogni, R., & Basosi, R. (1991). EPR and Electrochemical study of Copper Complexes with Phenanthrolines and Cinnamate ligands. INORGANICA CHIMICA ACTA, 184, 185-189.

EPR and Electrochemical study of Copper Complexes with Phenanthrolines and Cinnamate ligands

POGNI, REBECCA;BASOSI, RICCARDO
1991

Abstract

Solid state and solution EPR and electrochemical studies have been carried out on a series of complexes of copper(II) with differently substituted Phenanthrolines and cinnamate ligands. Spectra were recorded on binary complexes with cinnamate ligand and on a series of ternary complexes with the same anion and 1,10-Phenanthroline, 2,9-dimethyl-1,10-o-Phenanthroline or 4,7-dimethyl-1,10-o-Phenanthroline additional ligands, respectively. The electrochemistry of the same copper complexes was studied in N,N-dimethylformamide solvent. The results of both EPR and electrochemical experimetns can be correlated with electronic and steric effects attributable to the methyl substituents on the Phenanthroline ligand
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11365/32336
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