A collection of nickelocene and cobaltocene analogs with one or two nickelafluorenyl rings has been recently synthesized starting from 9-nickelafluorenyllithium complex. The redox ability of the whole series of derivates has been investigated by electrochemical techniques, and the nature of the frontier orbitals responsible for the electron transfer activity of this class of compounds has been supported by extended Hückel calculations.
Rossi, F., Fabrizi De Biani, F., Zanello, P., Buchalski, P. (2009). The redox behavior of 9-nickelafluorenyl sandwich complexes. JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 13(10), 1505-1510 [10.1007/s10008-009-0833-2].
The redox behavior of 9-nickelafluorenyl sandwich complexes
Fabrizi De Biani, Fabrizia;Zanello, Piero;
2009-01-01
Abstract
A collection of nickelocene and cobaltocene analogs with one or two nickelafluorenyl rings has been recently synthesized starting from 9-nickelafluorenyllithium complex. The redox ability of the whole series of derivates has been investigated by electrochemical techniques, and the nature of the frontier orbitals responsible for the electron transfer activity of this class of compounds has been supported by extended Hückel calculations.
| File | Dimensione | Formato | |
|---|---|---|---|
|
fulltext.pdf
non disponibili
Tipologia:
Post-print
Licenza:
NON PUBBLICO - Accesso privato/ristretto
Dimensione
221.74 kB
Formato
Adobe PDF
|
221.74 kB | Adobe PDF | Visualizza/Apri Richiedi una copia |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
https://hdl.handle.net/11365/22660
Attenzione
Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo