A new polymer based on a functionalized benzofulvene moiety has been synthesized by spontaneous polymerization of the monomer in the solid state. This polymer shows a very high molar mass, high solubility in the most common organic solvents, and thermoreversible polymerization properties. An interesting application in synthesis is reported.
Cappelli, A., Pericot Mohr, G., Anzini, M., Vomero, S., Donati, A., Casolaro, M., et al. (2003). Synthesis and Characterization of a New Benzofulvene Polymer Showing a Thermoreversible Polymerization Behavior. JOURNAL OF ORGANIC CHEMISTRY, 68(24), 9473-9476 [10.1021/jo035104h].
Synthesis and Characterization of a New Benzofulvene Polymer Showing a Thermoreversible Polymerization Behavior
Cappelli, Andrea;Anzini, Maurizio;Vomero, Salvatore;Donati, Alessandro;Casolaro, Mario;Giorgi, Gianluca;
2003-01-01
Abstract
A new polymer based on a functionalized benzofulvene moiety has been synthesized by spontaneous polymerization of the monomer in the solid state. This polymer shows a very high molar mass, high solubility in the most common organic solvents, and thermoreversible polymerization properties. An interesting application in synthesis is reported.
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https://hdl.handle.net/11365/20293
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