Compound [Pt6(μ-PtBu2)4(CO)Fc2] is prepared in good yields by the CuI-catalyzed coupling of two equivalents of ethynylferrocene with the hexanuclear cluster [Pt6(μ-PtBu2)4(CO)4Cl2]. Electrochemical and spectroelectrochemical data show the presence of photoelectrochemically triggered electron transfer from the {Pt6} core to the peripheral ferrocenyl subunits.

Albinati, A., FABRIZI DE BIANI, F., Leoni, P., Marchetti, L., Pasquali, M., Rizzato, S., et al. (2005). Redox control of light-induced platinum-cluster-to-iron charge transfer in a bis(ferrocenylethynyl)-substituted hexanuclear platinum derivative. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 44, 5701-5705 [10.1002/anie.200501714].

Redox control of light-induced platinum-cluster-to-iron charge transfer in a bis(ferrocenylethynyl)-substituted hexanuclear platinum derivative

FABRIZI DE BIANI, FABRIZIA;ZANELLO, PIERO
2005-01-01

Abstract

Compound [Pt6(μ-PtBu2)4(CO)Fc2] is prepared in good yields by the CuI-catalyzed coupling of two equivalents of ethynylferrocene with the hexanuclear cluster [Pt6(μ-PtBu2)4(CO)4Cl2]. Electrochemical and spectroelectrochemical data show the presence of photoelectrochemically triggered electron transfer from the {Pt6} core to the peripheral ferrocenyl subunits.
2005
Albinati, A., FABRIZI DE BIANI, F., Leoni, P., Marchetti, L., Pasquali, M., Rizzato, S., et al. (2005). Redox control of light-induced platinum-cluster-to-iron charge transfer in a bis(ferrocenylethynyl)-substituted hexanuclear platinum derivative. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 44, 5701-5705 [10.1002/anie.200501714].
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11365/20200