The ansa-ferrocene complex [1,1‘-fc(Bbipy)2O](PF6)2 {[5](PF6)2; fc = (η5-C5H4)2Fe} has been synthesized and structurally characterized. Electronic communication between the two 2,2‘-bipyridylboronium substituents was observed, suggesting the reduced forms [5]+ and [5]- to be partially delocalized redox intermediates.
Ding, L., Ma, K.B., Fabrizi De Biani, F., Bolte, M., Zanello, P., Wagner, M. (2001). Electronic communication in a novel five-step redox system. ORGANOMETALLICS, 20(6), 1041-1043 [10.1021/om000969w].
Electronic communication in a novel five-step redox system
Fabrizi De Biani, Fabrizia;Zanello, Piero;
2001-01-01
Abstract
The ansa-ferrocene complex [1,1‘-fc(Bbipy)2O](PF6)2 {[5](PF6)2; fc = (η5-C5H4)2Fe} has been synthesized and structurally characterized. Electronic communication between the two 2,2‘-bipyridylboronium substituents was observed, suggesting the reduced forms [5]+ and [5]- to be partially delocalized redox intermediates.
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https://hdl.handle.net/11365/20012
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