Longitudinal and transverse relaxation rates of ligand nuclei have been measured and their pH dependence has been investigated in terms of the dynamics of the MnII-L-histidine equilibrium. A careful analysis of the relative weights of dipolar and scalar contributions to the observed relaxation rates has been performed and the results related to changes in the correlation times.
Basosi, R., Laschi, F., Rossi, C. (1981). Proton NMR relaxation study of the Manganese(II)-L-histidine complex. Analysis of pH dependence and correlation times. JOURNAL OF THE CHEMICAL SOCIETY. FARADAY TRANSACTIONS I, 77(10), 2361-2365 [10.1039/F19817702361].
Proton NMR relaxation study of the Manganese(II)-L-histidine complex. Analysis of pH dependence and correlation times
Basosi, Riccardo;Laschi, Franco;Rossi, Claudio
1981-01-01
Abstract
Longitudinal and transverse relaxation rates of ligand nuclei have been measured and their pH dependence has been investigated in terms of the dynamics of the MnII-L-histidine equilibrium. A careful analysis of the relative weights of dipolar and scalar contributions to the observed relaxation rates has been performed and the results related to changes in the correlation times.
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https://hdl.handle.net/11365/17611
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