A Morita-Baylis-Hillman acetate was dimerized by a click-chemistry Copper(i)-Catalysed Azide-Alkyne Cycloaddition (CuAAC) reaction employing a tri(ethylene glycol) diazide derivative to obtain a dimeric MBHA derivative. The reaction of this dimeric MBHA derivative with n-butylamine afforded a photoisomerizable macrocyclic crown ether-paracyclophane hybrid architecture that is potentially useful in a large variety of applications as well as those already well-known for crown ethers.A tri(ethylene glycol)-tethered MBHA dimer was synthesized and found to react with n-butylamine leading to the formation of macrocyclic crown ether-paracyclophane hybrid structures that could be modulated by light.

Saletti, M., Venditti, J., Paolino, M., Zacchei, A., Giuliani, G., Giorgi, G., et al. (2023). A tri(ethylene glycol)-tethered Morita-Baylis-Hillman dimer in the formation of macrocyclic crown ether-paracyclophane hybrid structures. RSC ADVANCES, 13(51), 35773-35780 [10.1039/d3ra06792k].

A tri(ethylene glycol)-tethered Morita-Baylis-Hillman dimer in the formation of macrocyclic crown ether-paracyclophane hybrid structures

Saletti, Mario;Venditti, Jacopo;Paolino, Marco;Giuliani, Germano;Giorgi, Gianluca;Bonechi, Claudia;Donati, Alessandro;Cappelli, Andrea
2023-01-01

Abstract

A Morita-Baylis-Hillman acetate was dimerized by a click-chemistry Copper(i)-Catalysed Azide-Alkyne Cycloaddition (CuAAC) reaction employing a tri(ethylene glycol) diazide derivative to obtain a dimeric MBHA derivative. The reaction of this dimeric MBHA derivative with n-butylamine afforded a photoisomerizable macrocyclic crown ether-paracyclophane hybrid architecture that is potentially useful in a large variety of applications as well as those already well-known for crown ethers.A tri(ethylene glycol)-tethered MBHA dimer was synthesized and found to react with n-butylamine leading to the formation of macrocyclic crown ether-paracyclophane hybrid structures that could be modulated by light.
2023
Saletti, M., Venditti, J., Paolino, M., Zacchei, A., Giuliani, G., Giorgi, G., et al. (2023). A tri(ethylene glycol)-tethered Morita-Baylis-Hillman dimer in the formation of macrocyclic crown ether-paracyclophane hybrid structures. RSC ADVANCES, 13(51), 35773-35780 [10.1039/d3ra06792k].
File in questo prodotto:
File Dimensione Formato  
d3ra06792k.pdf

accesso aperto

Descrizione: Articolo
Tipologia: PDF editoriale
Licenza: Creative commons
Dimensione 1.07 MB
Formato Adobe PDF
1.07 MB Adobe PDF Visualizza/Apri

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11365/1253936