Hydroformylation of alkenes can be carried out in a few minutes under microwave activation at a relatively low pressure (40 psi) using commercially available catalysts and ligands. The 80 mL vial of a Discover microwave oven was connected to a cylinder of CO and H2, and after filling the reactor at 40 psi, a mixture of an alkene, the Wilkinson catalyst, and XANTPHOS was submitted to microwave irradiation giving, after 4 min, high conversion into the corresponding aldehyde without formation of the isomerized alkene. © 2006 American Chemical Society.
Petricci, E., Mann, A., Schoenfelder, A., Rota, A., Taddei, M. (2006). Microwaves make hydroformylation a rapid and easy process. ORGANIC LETTERS, 8(17), 3725-3727 [10.1021/ol061312v].
Microwaves make hydroformylation a rapid and easy process
PETRICCI, ELENA;TADDEI, MAURIZIO
2006-01-01
Abstract
Hydroformylation of alkenes can be carried out in a few minutes under microwave activation at a relatively low pressure (40 psi) using commercially available catalysts and ligands. The 80 mL vial of a Discover microwave oven was connected to a cylinder of CO and H2, and after filling the reactor at 40 psi, a mixture of an alkene, the Wilkinson catalyst, and XANTPHOS was submitted to microwave irradiation giving, after 4 min, high conversion into the corresponding aldehyde without formation of the isomerized alkene. © 2006 American Chemical Society.File | Dimensione | Formato | |
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https://hdl.handle.net/11365/1000682
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