The photochemistry of some 3,5-disubstituted 1,2,4-oxadiazoles in the presence of 2,3-dimethyl-2-butene has been investigated. The irradiation in acetonitrile yielded differently substituted N-imidoyl-aziridines through an aziridination reaction involving an acyliminonitrene intermediate. Pyrolysis of N-imidoyl-aziridines produced the corresponding N-allylamidines through a ring opening process. © 2007 The Japan Institute of Heterocyclic Chemistry.
Palumbo Piccionello, A., Pibiri, I., Pace, A., Raccuglia, R.A., Buscemi, S., Vivona, N., et al. (2007). On the photoreaction of some 1,2,4-oxadiazoles in the presence of2,3-dimethyl-2-butene. Synthesis of N-imidoyl-aziridines. HETEROCYCLES, 71(7), 1529-1537 [10.3987/com-07-11040].
On the photoreaction of some 1,2,4-oxadiazoles in the presence of2,3-dimethyl-2-butene. Synthesis of N-imidoyl-aziridines
Giorgi, G.
2007-01-01
Abstract
The photochemistry of some 3,5-disubstituted 1,2,4-oxadiazoles in the presence of 2,3-dimethyl-2-butene has been investigated. The irradiation in acetonitrile yielded differently substituted N-imidoyl-aziridines through an aziridination reaction involving an acyliminonitrene intermediate. Pyrolysis of N-imidoyl-aziridines produced the corresponding N-allylamidines through a ring opening process. © 2007 The Japan Institute of Heterocyclic Chemistry.
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https://hdl.handle.net/11365/9904
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