An appealingly wide set of redox couples ranging from -1.74 to -0.35 V based on a metallabisdicarbollide derivative, [M(C2B9H11-yIy)2]- (M = Co, Fe), each being distinguished from the former by near 0.15 V and all having the same structure have been demonstrated. The redox active methyl viologen moiety ([MV]2+) has been used as a benchmark.
Tarrés, M., Arderiu, V.S., Zaulet, A., Viñas, C., FABRIZI DE BIANI, F., Teixidor, F. (2015). How to get the desired reduction voltage in a single framework! Metallacarborane as an optimal probe for sequential voltage tuning. DALTON TRANSACTIONS, 44(26), 11690-11695 [10.1039/C5DT01464F].
How to get the desired reduction voltage in a single framework! Metallacarborane as an optimal probe for sequential voltage tuning
FABRIZI DE BIANI, FABRIZIA;
2015-01-01
Abstract
An appealingly wide set of redox couples ranging from -1.74 to -0.35 V based on a metallabisdicarbollide derivative, [M(C2B9H11-yIy)2]- (M = Co, Fe), each being distinguished from the former by near 0.15 V and all having the same structure have been demonstrated. The redox active methyl viologen moiety ([MV]2+) has been used as a benchmark.
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https://hdl.handle.net/11365/983458