A series of ethers has been prepared whose structures are related to tetrahydropyranyl and tetrahydrofuranyl derivatives with floral odors by replacement of either one of the two oxygen atoms with a methylene group. 2-Substituted tetrahydropyrans and tetrahydrofurans, as well as cyclohexyl and cyclopentyl ethers, have thus been obtained by substitution of the exocyclic or the endocyclic oxygen, respectively. None of the compounds exhibited a pure floral odor, although in several of them this note was present as a secondary character. The data contribute to a better understanding between structure and floral odor.
Anselmi, C., Centini, M., Mariani, M., Napolitano, E., Sega, A., Pelosi, P. (1994). Synthesis of ethers related to some floral odorants: effect of oxygen/carbon replacement. JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 42(12), 2876-2879 [10.1021/jf00048a042].
Synthesis of ethers related to some floral odorants: effect of oxygen/carbon replacement.
ANSELMI, CECILIA;CENTINI, MARISANNA;SEGA, ALESSANDRO;
1994-01-01
Abstract
A series of ethers has been prepared whose structures are related to tetrahydropyranyl and tetrahydrofuranyl derivatives with floral odors by replacement of either one of the two oxygen atoms with a methylene group. 2-Substituted tetrahydropyrans and tetrahydrofurans, as well as cyclohexyl and cyclopentyl ethers, have thus been obtained by substitution of the exocyclic or the endocyclic oxygen, respectively. None of the compounds exhibited a pure floral odor, although in several of them this note was present as a secondary character. The data contribute to a better understanding between structure and floral odor.
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https://hdl.handle.net/11365/49380
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