In this paper we discuss the mechanistic importance of surface crossings in various types of organic photochemical reactions which include the photocycloaddition of alkenes and the photochemistry of butadiene and acrolein. We discuss both the role of conical intersections which occur between states of the same multiplicity (most commonly singlet-singlet) and of intersystem crossings that occur between states of different multiplicity (typically singlet-triplet).
Bernardi, F., Olivucci, M., Robb, M.A. (1995). Following reaction paths in organic photochemistry: The special role of surface crossings. PURE AND APPLIED CHEMISTRY, 67(1), 17-24 [10.1351/pac199567010017].
Following reaction paths in organic photochemistry: The special role of surface crossings
Olivucci, Massimo;
1995-01-01
Abstract
In this paper we discuss the mechanistic importance of surface crossings in various types of organic photochemical reactions which include the photocycloaddition of alkenes and the photochemistry of butadiene and acrolein. We discuss both the role of conical intersections which occur between states of the same multiplicity (most commonly singlet-singlet) and of intersystem crossings that occur between states of different multiplicity (typically singlet-triplet).
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https://hdl.handle.net/11365/35058
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