Selective proton-carbon nuclear Overhauser effect (NOE) measurements have been widely used to analyse through-space proton-carbon interactions. Intermolecular interactions between adenosine and thymidine have been studied by means of selective {H}C-NOE spectroscopy. Moreover, the role of proton chemical exchange in determining {H}C-NOE has been considered. A combined use of homo- and hetero-nuclear selective NOE to account the chemical exchange contribution to the experimental {H}C-NOE has been proposed.
Rossi, C., Niccolai, N., Prugnola, A., Laschi, F. (1987). Selective H-1-c-13 and H-1-h-1 Nuclear Overhauser Enhancement Studies of Adenosine Thymidine Interaction In Solution. JOURNAL OF THE CHEMICAL SOCIETY. FARADAY TRANSACTIONS I, 83(6), 1731-1738 [10.1039/f19878301731].
Selective H-1-c-13 and H-1-h-1 Nuclear Overhauser Enhancement Studies of Adenosine Thymidine Interaction In Solution
Rossi, Claudio;Niccolai, Neri;
1987-01-01
Abstract
Selective proton-carbon nuclear Overhauser effect (NOE) measurements have been widely used to analyse through-space proton-carbon interactions. Intermolecular interactions between adenosine and thymidine have been studied by means of selective {H}C-NOE spectroscopy. Moreover, the role of proton chemical exchange in determining {H}C-NOE has been considered. A combined use of homo- and hetero-nuclear selective NOE to account the chemical exchange contribution to the experimental {H}C-NOE has been proposed.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
https://hdl.handle.net/11365/34062
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