N-tosyl phenylaziridines are opened regioselectively with allylsilanes in presence of BF3.Et(2)O to form gamma-amino olefins. During the reaction a formal [3+2] cycloaddition produced the corresponding pyrrolidines, amenable to the open chain compounds with TBAF. Copyright (C) 1996 Published by Elsevier Science
Schneider, M.R., Mann, A., Taddei, M. (1996). Ring opening of phenylaziridines with allylsilanes. TETRAHEDRON LETTERS, 37(47), 8493-8496 [10.1016/0040-4039(96)01975-2].
Ring opening of phenylaziridines with allylsilanes
Taddei, Maurizio
1996-01-01
Abstract
N-tosyl phenylaziridines are opened regioselectively with allylsilanes in presence of BF3.Et(2)O to form gamma-amino olefins. During the reaction a formal [3+2] cycloaddition produced the corresponding pyrrolidines, amenable to the open chain compounds with TBAF. Copyright (C) 1996 Published by Elsevier Science
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https://hdl.handle.net/11365/31391
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