Bromoallenes 3a and 3b derived from (D)-Serine undergo S(N)2' alkylation with organo copper reagents to give alkynyl amino alcohol derivatives. These compounds can be further transformed into blanched enantiomerically enriched alpha-amino acids as, for example (L)-Isolcucine and (L)-Alloisoleucine.

F., D., A., M., Taddei, M., & C. G., W. (1994). 1,3-diastereocontrol With Bromoallenes - Synthesis of Enantiomerically Pure Beta-branched Alpha-amino-acids. TETRAHEDRON LETTERS, 35, 7775-7778 [10.1016/S0040-4039(00)77369-2].

1,3-diastereocontrol With Bromoallenes - Synthesis of Enantiomerically Pure Beta-branched Alpha-amino-acids

TADDEI, MAURIZIO;
1994

Abstract

Bromoallenes 3a and 3b derived from (D)-Serine undergo S(N)2' alkylation with organo copper reagents to give alkynyl amino alcohol derivatives. These compounds can be further transformed into blanched enantiomerically enriched alpha-amino acids as, for example (L)-Isolcucine and (L)-Alloisoleucine.
F., D., A., M., Taddei, M., & C. G., W. (1994). 1,3-diastereocontrol With Bromoallenes - Synthesis of Enantiomerically Pure Beta-branched Alpha-amino-acids. TETRAHEDRON LETTERS, 35, 7775-7778 [10.1016/S0040-4039(00)77369-2].
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11365/31204
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