Allylsilanes preapared from alpha-aminoacids react with acyl chlorides in the presence of TiCl4 to give unsaturated amino ketones, easily transformed into pyrrolidine derivatives, whereas addition to aldehydes gave 2,6-disubstituted tetrahydropyridines.
Franciotti, M., Mann, A., Mordini, A., Taddei, M. (1993). Allylsilanes Derived From Amino-acids In the Synthesis of Piperidine and Pyrrolidine Derivatives. TETRAHEDRON LETTERS, 34(8), 1355-1358 [10.1016/S0040-4039(00)91794-5].
Allylsilanes Derived From Amino-acids In the Synthesis of Piperidine and Pyrrolidine Derivatives
Taddei, Maurizio
1993-01-01
Abstract
Allylsilanes preapared from alpha-aminoacids react with acyl chlorides in the presence of TiCl4 to give unsaturated amino ketones, easily transformed into pyrrolidine derivatives, whereas addition to aldehydes gave 2,6-disubstituted tetrahydropyridines.
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