Different silylating reagents with an optically active ligand bondedto the silicon centre have been synthesized starting from (1R) (-) myrtenal. The key step of the synthesis is the stereocontrolled 1,4 addition of phenyl-demethylsilyl-cuprate to the α,β unsaturated aldehyde. © 1987.
Coppi, L., Ricci, A., Taddei, M. (1987). C-centered Optically-active Organosilanes .1. Synthesis of New Silylated Chiral Auxiliaries. TETRAHEDRON LETTERS, 28(9), 965-968 [10.1016/S0040-4039(00)95888-X].
C-centered Optically-active Organosilanes .1. Synthesis of New Silylated Chiral Auxiliaries
Taddei, Maurizio
1987-01-01
Abstract
Different silylating reagents with an optically active ligand bondedto the silicon centre have been synthesized starting from (1R) (-) myrtenal. The key step of the synthesis is the stereocontrolled 1,4 addition of phenyl-demethylsilyl-cuprate to the α,β unsaturated aldehyde. © 1987.File in questo prodotto:
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