An extensive study on the reactivity of 2-tributylstannyl-1,3-butadiene with dienophiles is reported. The presence of a Lewis acid seems to be crucial in the regiochemical control of the cycloaddition. One example of further functionalisation of the adduct through its CSn bond is also reported. A study on cycloadditions of 2-tributylstannyl-1, 3-butadiene with symmetrical and unsymmetrical dienophiles is reported.
Taddei, M., Mann, A. (1986). Cycloaddition Reactions of 2-tributylstannyl-1,3-butadiene. TETRAHEDRON LETTERS, 27(25), 2913-2916 [10.1016/S0040-4039(00)84679-1].
Cycloaddition Reactions of 2-tributylstannyl-1,3-butadiene
Taddei, Maurizio;
1986-01-01
Abstract
An extensive study on the reactivity of 2-tributylstannyl-1,3-butadiene with dienophiles is reported. The presence of a Lewis acid seems to be crucial in the regiochemical control of the cycloaddition. One example of further functionalisation of the adduct through its CSn bond is also reported. A study on cycloadditions of 2-tributylstannyl-1, 3-butadiene with symmetrical and unsymmetrical dienophiles is reported.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
https://hdl.handle.net/11365/30714
Attenzione
Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo