(E)-Methoxy alkenes derived from N-Boc or NCbz alpha-amino acids undergo stereoselective addition of phenyl selenyl chloride in the presence of Ti(Oi-Pr)(4) and LiCl to give the corresponding phenylselenyl aldehydes that can be easily transformed into new enantiomericalIy pure amino acids containing an aziridine ring. (C) 1999 Elsevier Science Ltd. All rights reserved.
Demarcus, M., Filigheddu, S.N., Mann, A., Taddei, M. (1999). Stereoselective addition of phenyl selenyl chloride to methoxy alkenes derived from N-protected chiral alpha-amino acids. TETRAHEDRON LETTERS, 40(23), 4417-4420 [10.1016/S0040-4039(99)00761-3].
Stereoselective addition of phenyl selenyl chloride to methoxy alkenes derived from N-protected chiral alpha-amino acids
Taddei, Maurizio
1999-01-01
Abstract
(E)-Methoxy alkenes derived from N-Boc or NCbz alpha-amino acids undergo stereoselective addition of phenyl selenyl chloride in the presence of Ti(Oi-Pr)(4) and LiCl to give the corresponding phenylselenyl aldehydes that can be easily transformed into new enantiomericalIy pure amino acids containing an aziridine ring. (C) 1999 Elsevier Science Ltd. All rights reserved.
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https://hdl.handle.net/11365/30440
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