The protonation and complex formation of some basic polymers have been studied in aqueous solution by potentiometric, calorimetric, spectrophotometric and viscosimetric techniques. Specific methods for the treatment of either ‘sharp’ or ‘apparent’ thermodynamic functions in polyelectrolyte bearing one or two basic groups in the repeating unit have been developed. The results are related to structure features and presence of various types of chemical function besides the aminic function.
Barbucci, R., Casolaro, M., Corezzi, S., Nocentini, M., Ferruti, P. (1985). New developments in MacroInorganics. The thermodynamics of basic polymers. POLYMER, 26(9), 1353-1358 [10.1016/0032-3861(85)90311-8].
New developments in MacroInorganics. The thermodynamics of basic polymers
Barbucci, R.;Casolaro, Mario;Corezzi, S.;
1985-01-01
Abstract
The protonation and complex formation of some basic polymers have been studied in aqueous solution by potentiometric, calorimetric, spectrophotometric and viscosimetric techniques. Specific methods for the treatment of either ‘sharp’ or ‘apparent’ thermodynamic functions in polyelectrolyte bearing one or two basic groups in the repeating unit have been developed. The results are related to structure features and presence of various types of chemical function besides the aminic function.
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https://hdl.handle.net/11365/29504
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