Three copper complexes containing β-cyclodextrin (βCD) derivatives as ligands [mono-6-methylamino-6-deoxy- βCD dithiocarbamate (CDTC), mono-6-histamino-6-deoxy-βCD (CDHM) and mono-6-Nα-arginyl-6-deoxy-βCD (CDARG)] have been studied by electron paramagnetic resonance. The spectra have been recorded at X- and S-bands and different temperatures and simulated to obtain the best set of magnetic parameters. Some structural characteristics of the complexes are proposed on the basis of dynamic and covalency parameters obtained from simulation.
Fragoso, A., Baratto, M.C., Diaz, A., Rodriguez, Y., Pogni, R., Basosi, R., et al. (2004). Electron paramagnetic resonance studies on copper(II)-cyclodextrin systems. DALTON TRANSACTIONS, 4(9), 1456-1460 [10.1039/ b402185a].
Electron paramagnetic resonance studies on copper(II)-cyclodextrin systems
Baratto, M. C.;Pogni, Rebecca;Basosi, Riccardo;
2004-01-01
Abstract
Three copper complexes containing β-cyclodextrin (βCD) derivatives as ligands [mono-6-methylamino-6-deoxy- βCD dithiocarbamate (CDTC), mono-6-histamino-6-deoxy-βCD (CDHM) and mono-6-Nα-arginyl-6-deoxy-βCD (CDARG)] have been studied by electron paramagnetic resonance. The spectra have been recorded at X- and S-bands and different temperatures and simulated to obtain the best set of magnetic parameters. Some structural characteristics of the complexes are proposed on the basis of dynamic and covalency parameters obtained from simulation.
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https://hdl.handle.net/11365/22862
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