A method for the determination of hexane-1,6-diyl diisocyanate 1-isocyanato- 3-isocyanatomethyl-3,5,5-trimethylcyclohexane, toluene-2,4-diyl diisocyanate and toluene-2,6-diyl diisocyanate in air by differential-pulse polarography (DPP) is described. The monomers are derivatized with 4-nitro-N-propylbenzylamine (nitro reagent). The excess of nitro reagent is removed by using solid-phase extraction columns and the ureido derivatives are determined by DPP in 0.2 mol dm-3 KOH [methanol-water (80 + 20)] as the total concentration of diisocyanate in the sample.
Corbini, G., Corti, P., Dreassi, E., Nucci, L., Sciarra, G. (1991). Determination of diisocyanate monomers in air by differential-pulse polarography. ANALYST, 116(7), 731-734 [10.1039/AN9911600731].
Determination of diisocyanate monomers in air by differential-pulse polarography
CORBINI G.;CORTI P.;DREASSI E.;
1991-01-01
Abstract
A method for the determination of hexane-1,6-diyl diisocyanate 1-isocyanato- 3-isocyanatomethyl-3,5,5-trimethylcyclohexane, toluene-2,4-diyl diisocyanate and toluene-2,6-diyl diisocyanate in air by differential-pulse polarography (DPP) is described. The monomers are derivatized with 4-nitro-N-propylbenzylamine (nitro reagent). The excess of nitro reagent is removed by using solid-phase extraction columns and the ureido derivatives are determined by DPP in 0.2 mol dm-3 KOH [methanol-water (80 + 20)] as the total concentration of diisocyanate in the sample.
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https://hdl.handle.net/11365/20695
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