Catalytic activity of [L2.Zn][NO3]2 (L = spiro-N3P3[O2C12 H 8g][N(CH3)NH2]) towards the hydrolysis of two phosphodiesters, [bis(p-nitrophenyl)phosphate, bNPP] and [2-(hydroxypropyl)-p- nitro-phenyl phosphate, hNPP] has been examined. While the rate of hydrolysis of the former is accelerated over a million-fold, the rate of hydrolysis of the latter also is enhanced considerably. Detailed kinetic evaluation of these reactions has been carried out and all the kinetic parameters including the Michaelis-Menten parameters are reported. The catalyst [L2.Zn] [NO3]2 has also been found to be an effective nuclease. Relaxation of supercoiled plasmid DNA, pBR322, occurs in presence of [L 2.Zn][NO3]2 without the need for any exogenous reagents. © Indian Academy of Sciences.
Verma, V., Betti, G. (2005). Sampling Errors for Measures of Inequality and Poverty. In Classification and Data Analysis 2005 ¬ Book of Short Papers (pp.175-179). Indian Academy of Sciences [10.1007/BF03356113].
Sampling Errors for Measures of Inequality and Poverty
Betti G.
2005-01-01
Abstract
Catalytic activity of [L2.Zn][NO3]2 (L = spiro-N3P3[O2C12 H 8g][N(CH3)NH2]) towards the hydrolysis of two phosphodiesters, [bis(p-nitrophenyl)phosphate, bNPP] and [2-(hydroxypropyl)-p- nitro-phenyl phosphate, hNPP] has been examined. While the rate of hydrolysis of the former is accelerated over a million-fold, the rate of hydrolysis of the latter also is enhanced considerably. Detailed kinetic evaluation of these reactions has been carried out and all the kinetic parameters including the Michaelis-Menten parameters are reported. The catalyst [L2.Zn] [NO3]2 has also been found to be an effective nuclease. Relaxation of supercoiled plasmid DNA, pBR322, occurs in presence of [L 2.Zn][NO3]2 without the need for any exogenous reagents. © Indian Academy of Sciences.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
https://hdl.handle.net/11365/17000
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