The curious effect of potassium fluoride on glycerol carbonate. How salts can influence the structuredness of organic solvents

Glycerol carbonate (4-hydroxymethyl-1,3-dioxolan-2-one, shortly GC) is a dense, viscous, water soluble solvent. The high dielectric constant and dipole moment make it a suitable non-aqueous green solvent for several salts in different applications. GC dissolves significant amounts of inorganic salts such as KF. The saturation of GC with KF leads to the formation of a viscous liquid at room temperature. In this paper, we report on conductivity, rheology, differential scanning calorimetry and infrared spectroscopy experiments that indicate the formation of a glassy liquid where GC molecules and KF ion pairs are intercalated in a firm and ordered tridimensional structure, stabilized by hydrogen bonding and strong ion-dipole interactions. (C) 2018 Elsevier B.V. All rights reserved.