Here we show a time-programmed and autonomous synthesis of zeolitic imidazole framework-8 (ZIF-8) using a methylene glycol-sulfite clock reaction. The induction period of the driving clock reaction, thus, the appearance of the ZIF-8 can be adjusted by the initial concentration of one reagent of the chemical clock. The autonomously synthesized ZIF-8 showed excellent morphology and crystallinity.
Nemet, N., Hollo, G., Schuszter, G., Horvath, D., Toth, A., Rossi, F., et al. (2022). Application of a chemical clock in material design: chemically programmed synthesis of zeolitic imidazole framework-8. CHEMICAL COMMUNICATIONS, 58(38), 5777-5780 [10.1039/d2cc01139e].
Application of a chemical clock in material design: chemically programmed synthesis of zeolitic imidazole framework-8
Rossi F.;
2022-01-01
Abstract
Here we show a time-programmed and autonomous synthesis of zeolitic imidazole framework-8 (ZIF-8) using a methylene glycol-sulfite clock reaction. The induction period of the driving clock reaction, thus, the appearance of the ZIF-8 can be adjusted by the initial concentration of one reagent of the chemical clock. The autonomously synthesized ZIF-8 showed excellent morphology and crystallinity.
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https://hdl.handle.net/11365/1208777
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