Galactose oxidase (GOase) was shown to oxidise several C2/C3 fluorinated galactose analogues. Interestingly, the enzyme was able to distinguish between the 2,3-tetrafluorinated galactose and its epimeric glucose analogue, and this represents the first reported biotransformation of a heavily fluorinated sugar. © 2011 The Royal Society of Chemistry.
Ioannou, A., Cini, E., Timofte, R.S., Flitsch, S.L., Turner, N.J., Linclau, B. (2011). Heavily fluorinated carbohydrates as enzyme substrates: Oxidation of tetrafluorinated galactose by galactose oxidase. CHEMICAL COMMUNICATIONS, 47(40), 11228-11230 [10.1039/c1cc13956h].
Heavily fluorinated carbohydrates as enzyme substrates: Oxidation of tetrafluorinated galactose by galactose oxidase
Cini, Elena;
2011-01-01
Abstract
Galactose oxidase (GOase) was shown to oxidise several C2/C3 fluorinated galactose analogues. Interestingly, the enzyme was able to distinguish between the 2,3-tetrafluorinated galactose and its epimeric glucose analogue, and this represents the first reported biotransformation of a heavily fluorinated sugar. © 2011 The Royal Society of Chemistry.
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https://hdl.handle.net/11365/1077874