The use of ancillary ligands resulted in the formation of (trans-[PtCl 3(OH2)N=C(OCH3)CH2CH 2CH22]+ (see structure), the first intermediate aqua species in the oxidation of platinum(II) to platinum(IV) to be isolated and characterized. In chloroform this complex, but not the corresponding chloro species, reacts with excess Cl- with O-demethylation of the ligands, indicating the importance of the coordinated water molecule.
Tamasi, G., Cini, R., Intini, F.P., Sivo, M.F., Natile, G. (2004). Unusual reactivity at a platinum center determined by the ligands and the solvent environment. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 43(38), 5081-5084 [10.1002/anie.200454111].
Unusual reactivity at a platinum center determined by the ligands and the solvent environment
Tamasi, Gabriella;Cini, Renzo;
2004-01-01
Abstract
The use of ancillary ligands resulted in the formation of (trans-[PtCl 3(OH2)N=C(OCH3)CH2CH 2CH22]+ (see structure), the first intermediate aqua species in the oxidation of platinum(II) to platinum(IV) to be isolated and characterized. In chloroform this complex, but not the corresponding chloro species, reacts with excess Cl- with O-demethylation of the ligands, indicating the importance of the coordinated water molecule.
| File | Dimensione | Formato | |
|---|---|---|---|
|
07-AngwChimie(2004)-PtTrans.pdf
non disponibili
Tipologia:
PDF editoriale
Licenza:
NON PUBBLICO - Accesso privato/ristretto
Dimensione
158.28 kB
Formato
Adobe PDF
|
158.28 kB | Adobe PDF | Visualizza/Apri Richiedi una copia |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
https://hdl.handle.net/11365/1025177