The use of ancillary ligands resulted in the formation of (trans-[PtCl 3(OH2)N=C(OCH3)CH2CH 2CH22]+ (see structure), the first intermediate aqua species in the oxidation of platinum(II) to platinum(IV) to be isolated and characterized. In chloroform this complex, but not the corresponding chloro species, reacts with excess Cl- with O-demethylation of the ligands, indicating the importance of the coordinated water molecule.

Tamasi, G., Cini, R., Intini, F.P., Sivo, M.F., & Natile, G. (2004). Unusual reactivity at a platinum center determined by the ligands and the solvent environment. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 43(38), 5081-5084 [10.1002/anie.200454111].

Unusual reactivity at a platinum center determined by the ligands and the solvent environment

Tamasi, Gabriella;Cini, Renzo;
2004

Abstract

The use of ancillary ligands resulted in the formation of (trans-[PtCl 3(OH2)N=C(OCH3)CH2CH 2CH22]+ (see structure), the first intermediate aqua species in the oxidation of platinum(II) to platinum(IV) to be isolated and characterized. In chloroform this complex, but not the corresponding chloro species, reacts with excess Cl- with O-demethylation of the ligands, indicating the importance of the coordinated water molecule.
Tamasi, G., Cini, R., Intini, F.P., Sivo, M.F., & Natile, G. (2004). Unusual reactivity at a platinum center determined by the ligands and the solvent environment. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 43(38), 5081-5084 [10.1002/anie.200454111].
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11365/1025177