The control of the charge distribution in a monolayer of switchable cobalt-dioxolene complexes undergoing Valence Tautomerism (VT) has been achieved by means of thermal and optical stimuli. Thiol-derivatised VT molecules have been grafted on polycrystalline gold surface as monolayers from solution. X-ray photoelectron spectroscopy and time-of-flight secondary ions mass spectrometry evidenced the formation of a covalent bond between intact VT molecules and the surface and excluded the presence of physisorbed molecules. X-ray absorption spectroscopy revealed that the temperature- and light-induced conversion profiles of the monolayer closely reproduce the ones found for the crystalline phase. This study demonstrates that a wet chemistry based approach allows to transfer switchable paramagnetic molecules at the nanoscale, widening the playground to develop new hybrid molecular based architectures for novel technologies.
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|Titolo:||Thermal and optical control of electronic states in a single layer of switchable paramagnetic molecules|
|Citazione:||Poneti, G., Poggini, L., Mannini, M., Cortigiani, B., Sorace, L., Otero, E., et al. (2015). Thermal and optical control of electronic states in a single layer of switchable paramagnetic molecules. CHEMICAL SCIENCE, 6(4), 2268-2274.|
|Appare nelle tipologie:||1.1 Articolo in rivista|
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