The chemical origin and mechanism of firefly bioluminescence were theoretically investigated. All kinds of oxyluciferines in keto or enol conformation were investigated by multireference theoretical methods as possible light emitters. The decomposition of dioxetane, dioxetanone, and firefly dioxetanone were studied as chemiluminescent prototypes at the multiconfigurational second-order perturbation level of theory (CASPT2)
Chen, S.F., Liu, Y.J., Liu, F.Y., De Vico, L., Lindh, R. (2010). Multireference calculations on the chemical origin and mechanism of firefly bioluminescence. In Abstracts of the 16th International Symposium on Bioluminescence and Chemiluminescence – (ISBC 2010) (pp.89-90). Hoboken : Wiley [10.1002/bio.1211].
Multireference calculations on the chemical origin and mechanism of firefly bioluminescence
De Vico, L.;
2010-01-01
Abstract
The chemical origin and mechanism of firefly bioluminescence were theoretically investigated. All kinds of oxyluciferines in keto or enol conformation were investigated by multireference theoretical methods as possible light emitters. The decomposition of dioxetane, dioxetanone, and firefly dioxetanone were studied as chemiluminescent prototypes at the multiconfigurational second-order perturbation level of theory (CASPT2)
| File | Dimensione | Formato | |
|---|---|---|---|
|
1211_ftp.pdf
non disponibili
Descrizione: Articolo principale
Tipologia:
PDF editoriale
Licenza:
NON PUBBLICO - Accesso privato/ristretto
Dimensione
9.7 MB
Formato
Adobe PDF
|
9.7 MB | Adobe PDF | Visualizza/Apri Richiedi una copia |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
https://hdl.handle.net/11365/1005997
Attenzione
Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo