For Copper(II) in biological systems, and even for small copper complexes in fluid solution at room temperature, the CW lineshapes are strongly influenced by molecular motion. the intermediate tumbling lineshapes for Cu(II) complexes have been analyzed using the stochastic Liouville equations. Various methods of analysing Cu(II) spectra are presented. Examples are given for complexes of pepetides, phenanthroline plus glutathione, bleomycin, and B-casomorphins. The methods could be extended to other paramagnetic metal ions.
Basosi, R., G., D.L., Pogni, R. (2005). Copper Biomolecules in Solution. In Biomedical EPR-Part A: Free Radicals, Metals, Medicine and Physiology (pp. 385-416). New York : Kluwer Academic Publishing.
Copper Biomolecules in Solution
BASOSI, RICCARDO;POGNI, REBECCA
2005-01-01
Abstract
For Copper(II) in biological systems, and even for small copper complexes in fluid solution at room temperature, the CW lineshapes are strongly influenced by molecular motion. the intermediate tumbling lineshapes for Cu(II) complexes have been analyzed using the stochastic Liouville equations. Various methods of analysing Cu(II) spectra are presented. Examples are given for complexes of pepetides, phenanthroline plus glutathione, bleomycin, and B-casomorphins. The methods could be extended to other paramagnetic metal ions.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
https://hdl.handle.net/11365/31709
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