Isotopic substitution with 15N and computer simulation have been used in elucidating the hyperfine structure of the EPR spectra of iron-dinitrosyl complexes in solution. Additional information for the identification of the binding sites and of the molecular structures of the complexes have been obtained from 1H and 13C Fourier transform NMR spectra. Carbazides, thiocarbazides, amino acids, and other amino derivatives have been taken into consideration as ligands for the Fe(NO)2 group.
Martini, G., Niccolai, N., Tiezzi, E. (1975). Molecular structures of iron-nitrosyl complexes on the basis of EPR and NMR spectra. THE JOURNAL OF PHYSICAL CHEMISTRY, 79(16), 1721-1725 [10.1021/j100583a023].
Molecular structures of iron-nitrosyl complexes on the basis of EPR and NMR spectra
Niccolai, N.;Tiezzi, E.
1975-01-01
Abstract
Isotopic substitution with 15N and computer simulation have been used in elucidating the hyperfine structure of the EPR spectra of iron-dinitrosyl complexes in solution. Additional information for the identification of the binding sites and of the molecular structures of the complexes have been obtained from 1H and 13C Fourier transform NMR spectra. Carbazides, thiocarbazides, amino acids, and other amino derivatives have been taken into consideration as ligands for the Fe(NO)2 group.
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https://hdl.handle.net/11365/33073
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